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《Biohydrometallurgical Recycling of Metals from Industrial Wastes》
从工业废物中回收金属生物湿法冶金
作者:
Hong Hocheng
Mital Chakankar
Umesh Jadhav
出版社:CRC
出版时间:2018年
《Biohydrometallurgical Recycling of Metals from Industrial Wastes》
《Biohydrometallurgical Recycling of Metals from Industrial Wastes》
《Biohydrometallurgical Recycling of Metals from Industrial Wastes》
《Biohydrometallurgical Recycling of Metals from Industrial Wastes》
目录
Preface xi
Authors xiii
Chapter 1 Introduction...........................................................................................1
1.1 Brief History of Industrial Progress and Generation
of Industrial Wastes....................................................................1
1.2 Threats of Metal-Containing Wastes to the Environment..........3
1.2.1 Lead...............................................................................6
1.2.2 Chromium......................................................................7
1.2.3 Arsenic..........................................................................7
1.2.4 Zinc................................................................................8
1.2.5 Cadmium.......................................................................8
1.2.6 Copper...........................................................................9
1.2.7 Mercury.........................................................................9
1.2.8 Nickel..........................................................................10
1.3 Advantages of Recycling..........................................................10
1.4 Conclusions..............................................................................12
References...........................................................................................13
Chapter 2 Generation and Composition of Various Metal-Containing
Industrial Wastes.................................................................................19
2.1 Introduction..............................................................................19
2.2 Electronic Wastes......................................................................19
2.2.1 Printed Circuit Boards.................................................20
2.2.2 Solders.........................................................................21
2.3 Energy Storage Wastes.............................................................22
2.3.1 Batteries.......................................................................22
2.3.1.1 Zinc–Manganese Dioxide Batteries.............23
2.3.1.2 Nickel–Cadmium Batteries..........................24
2.3.1.3 Nickel–Metal Hydride Batteries..................24
2.3.1.4 Lithium-Ion Batteries...................................25
2.3.2 Button Cell Batteries...................................................26
2.4 Metal Production Wastes..........................................................26
2.4.1 Slag..............................................................................26
2.4.2 Dust.............................................................................29
2.4.3 Foundry Sand..............................................................29
2.4.4 Electric Arc Furnace Dust...........................................31
2.5 Solar Photoelectricity Wastes...................................................31
2.5.1 Solar Panels.................................................................31
2.6 Power Plant and Incineration Plant Wastes..............................32
2.6.1 Thermal Power Plant Bottom and Fly Ash..................32
2.6.2 Municipal Solid Waste................................................34
2.6.3 Coal Cleaning or Beneficiation Waste.........................35
2.7 Petrochemical Wastes...............................................................36
2.7.1 Spent Petroleum Catalysts...........................................36
2.8 Sludge.......................................................................................37
2.8.1 Municipal Sewage Sludge...........................................37
2.8.2 Industrial Sludge.........................................................38
2.9 Lighting Wastes........................................................................38
2.9.1 Light-Emitting Diodes.................................................38
2.9.2 Mercury Light Bulb Wastes.........................................39
2.10 Automobile Wastes...................................................................40
2.11 Metal Speciation.......................................................................41
References...........................................................................................44
Chapter 3 Conventional Metal Recycling Techniques.........................................63
3.1 Introduction..............................................................................63
3.2 Methods for Metal Recovery....................................................64
3.2.1 Physical/Mechanical Methods.....................................64
3.2.1.1 Screening.....................................................64
3.2.1.2 Shape Separation.........................................64
3.2.1.3 Magnetic Separation....................................64
3.2.1.4 Electric Conductivity–Based Separation.....64
3.2.1.5 Density-Based Separation............................65
3.2.2 Pyrometallurgical Method...........................................65
3.2.3 Hydrometallurgical Method........................................66
3.2.4 Microbiological and Biochemical Recycling..............69
3.2.4.1 Microbial/Bioleaching Process....................70
3.2.4.2 Mechanisms Underlying the
Bioleaching Process.....................................72
3.3 Conclusion and Future Perspective..........................................83
References...........................................................................................84
Chapter 4 Recycling of Electronic Waste............................................................97
4.1 Introduction..............................................................................97
4.2 Bioleaching of Metals from E-Waste.......................................98
4.2.1 Solder..........................................................................98
4.2.2 Printed Circuit Boards (PCBs)..................................100
4.2.2.1 Microorganisms for Metal Recovery
from PCBs.................................................100
4.2.2.2 Recovery of Gold.......................................117
4.2.3 Kinetics of Metal Recovery.......................................124
4.2.4 Process Optimization for Metal Recovery................124
4.2.5 Use of Biosurfactants in Metal Recovery..................127
4.2.6 Leaching Process Using Enzymes.............................128
4.3 Conclusion..............................................................................130
References.........................................................................................130
Chapter 5 Recycling of Energy Storage Wastes.................................................137
5.1 Introduction............................................................................137
5.2 Bioleaching of Metals from Energy Storage Wastes..............137
5.2.1 Battery.......................................................................137
5.2.1.1 Lithium-Ion Batteries.................................137
5.2.1.2 Ni–Cd and Ni–MH Batteries.....................145
5.2.1.3 Zn–Mn Batteries........................................151
5.2.2 Button Cells...............................................................154
5.3 Conclusion..............................................................................155
References.........................................................................................156
Chapter 6 Recycling of Metal Production Wastes.............................................159
6.1 Introduction............................................................................159
6.2 Bioleaching of Slags...............................................................159
6.2.1 Cu Smelter Slags.......................................................159
6.2.2 Pb/Zn Slags...............................................................166
6.3 Bioleaching of Foundry Sand.................................................168
6.4 Bioleaching of Industrial Waste Dust.....................................169
6.4.1 Smelter Dust..............................................................169
6.4.2 EAF Dust...................................................................172
6.4.3 ESP Dust...................................................................173
6.4.4 Industrial Filter Dust.................................................173
6.5 Bioleaching of Industrial Waste Sludge.................................174
6.6 Conclusion..............................................................................174
References.........................................................................................174
Chapter 7 Recycling of Solar Electricity Waste.................................................179
7.1 Introduction............................................................................179
7.2 Bioleaching of Metals from Solar Electricity Waste..............180
7.3 Conclusion..............................................................................180
References.........................................................................................181
Chapter 8 Recycling of Thermal Power Generation Wastes..............................183
8.1 Introduction............................................................................183
8.2 Bioleaching of Thermal Power Generation Waste..................183
8.2.1 Microorganisms for Metal Recovery from Fly Ash..... 183
8.2.2 Process Optimization for Metal Recovery................198
8.2.3 Kinetics of Metal Recovery.......................................200
8.3 Conclusion..............................................................................200
References.........................................................................................201
Index 205
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