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《Hydrogen Fuel Cells for Road Vehicles》
道路车辆用氢燃料电池
作者:
Pasquale Corbo
Fortunato Migliardini
Ottorino Veneri
Istituto Motori
National Research Council of Italy
出版社:Springer
出版时间:2011年
《Hydrogen Fuel Cells for Road Vehicles》
《Hydrogen Fuel Cells for Road Vehicles》
《Hydrogen Fuel Cells for Road Vehicles》
《Hydrogen Fuel Cells for Road Vehicles》
目录
1 Possible Routes Towards Carbon-Free Vehicles. . . . . . . . . . . . . . . 1
1.1 Mobility Demands and Primary Energy Resources . . . . . . . . . . . 3
1.2 Internal Combustion Engines and Their Impact
on Air Quality . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
1.3 Climate Change and Carbon-Free Fuel Chance . . . . . . . . . . . . . 19
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
2 Hydrogen as Future Energy Carrier . . . . . . . . . . . . . . . . . . . . . . . 33
2.1 Hydrogen Production . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
2.1.1 Thermal Processes . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
2.1.2 Electrolytic Processes . . . . . . . . . . . . . . . . . . . . . . . . . . 48
2.1.3 Photolytic Processes. . . . . . . . . . . . . . . . . . . . . . . . . . . 53
2.2 Hydrogen Distribution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
2.3 Hydrogen Storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
2.3.1 Hydrogen Storage in High Compressed Gas Form . . . . . . 58
2.3.2 Hydrogen Storage in Liquid Cryogenic Form . . . . . . . . . 59
2.3.3 Hydrogen Storage in Solid Materials . . . . . . . . . . . . . . . 61
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
3 Fuel Cells for Automotive Applications . . . . . . . . . . . . . . . . . . . . . 71
3.1 Basic Concepts of Electrochemistry . . . . . . . . . . . . . . . . . . . . . 72
3.2 Proton Exchange Membrane Fuel Cells . . . . . . . . . . . . . . . . . . 76
3.2.1 The MEA: Membrane . . . . . . . . . . . . . . . . . . . . . . . . . 79
3.2.2 The MEA: Electrocatalysts . . . . . . . . . . . . . . . . . . . . . . 83
3.2.3 The MEA: GDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
3.2.4 The Bipolar Plates . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
3.3 Sensitivity of PEM Stacks to Operating Conditions . . . . . . . . . . 88
3.3.1 The Polarization Curve. . . . . . . . . . . . . . . . . . . . . . . . . 88
3.3.2 Effect of Operative Parameters on the
Polarization Curve . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
vii
3.4 Durability of PEM Fuel Cells . . . . . . . . . . . . . . . . . . . . . . . . . 97
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99
4 Design of Hydrogen Fuel Cell Systems for Road Vehicles . . . . . . . 103
4.1 Hydrogen Fuel Cell Systems: Preliminary Remarks . . . . . . . . . . 104
4.2 Hydrogen Feeling System . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106
4.3 Air Feeding System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108
4.4 Thermal Management System . . . . . . . . . . . . . . . . . . . . . . . . . 114
4.5 Water/Humidification Management System. . . . . . . . . . . . . . . . 116
4.6 Integrated Fuel Cell System: Efficiency, Dynamics, Costs . . . . . 121
4.6.1 FCS Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123
4.6.2 FCS Dynamics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
4.6.3 FCS Costs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128
5 Electric Vehicles in Hybrid Configuration. . . . . . . . . . . . . . . . . . . 131
5.1 Electric Vehicles: Preliminary Remarks . . . . . . . . . . . . . . . . . . 131
5.2 Electric Drives for Road Vehicles . . . . . . . . . . . . . . . . . . . . . . 133
5.2.1 DC Electric Machines . . . . . . . . . . . . . . . . . . . . . . . . . 134
5.2.2 AC Electric Machines . . . . . . . . . . . . . . . . . . . . . . . . . 136
5.2.3 Control and Power Electronics . . . . . . . . . . . . . . . . . . . 138
5.3 Storage Electrochemical Batteries . . . . . . . . . . . . . . . . . . . . . . 140
5.3.1 Main Operative Parameters of Batteries . . . . . . . . . . . . . 141
5.3.2 Main Characteristics of Different Types of Batteries . . . . 146
5.4 Alternative Energy Storage Systems . . . . . . . . . . . . . . . . . . . . . 154
5.4.1 Flywheels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154
5.4.2 Super Capacitors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
5.5 Hybrid Propulsion Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
5.5.1 Hybrid Thermal Electric Vehicles . . . . . . . . . . . . . . . . . 157
5.5.2 Solar Vehicles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
5.5.3 Vehicles Using Flywheels and Super Capacitors . . . . . . . 161
5.5.4 Fuel Cell Electric Vehicles . . . . . . . . . . . . . . . . . . . . . . 162
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
6 Case Study A: Fuel Cell Power Train for Mopeds. . . . . . . . . . . . . 167
6.1 Description of the 3.5 kW Fuel Power Train . . . . . . . . . . . . . . . 167
6.2 Efficiency Calculations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
6.3 FCS Characterization: Energy Losses in Steady
State Conditions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
6.4 Dynamic Performance of the FCS . . . . . . . . . . . . . . . . . . . . . . 176
6.5 Characterization of the Overall Power Train
on Driving Cycles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185
viii Contents
6.5.1 Analysis of the FCS Dynamic Behavior
on Driving Cycles . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185
6.5.2 Analysis of the Overall Propulsion System
on Driving Cycles . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198
7 Case Study B: Fuel Cell Power Train for Cars . . . . . . . . . . . . . . . 199
7.1 Description of the 30 kW Fuel Power Train . . . . . . . . . . . . . . . 199
7.2 FCS Characterization: Effect of Operative Parameters . . . . . . . . 203
7.3 Analysis of the Dynamic Behavior of the FCS . . . . . . . . . . . . . 210
7.3.1 Performance of the FCS During Load Variations. . . . . . . 211
7.3.2 Behavior of the FCS During Warm-up. . . . . . . . . . . . . . 219
7.4 Effect of Different Air Management Strategies . . . . . . . . . . . . . 223
7.5 Fuel Cell Power Train Tested on the R40 Driving Cycle . . . . . . 236
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240
Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241
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