《Biohydrometallurgical Recycling of Metals from Industrial Wastes》
《Biohydrometallurgical Recycling of Metals from Industrial Wastes》从工业废物中回收金属生物湿法冶金
作者：
Hong Hocheng
Mital Chakankar
Umesh Jadhav
出版社：CRC
出版时间：2018年
目录
Prefacexi
Authorsxiii
Chapter 1 Introduction...........................................................................................1
1.1 Brief History of Industrial Progress and Generation
of Industrial Wastes....................................................................1
1.2 Threats of Metal-Containing Wastes to the Environment..........3
1.2.1 Lead...............................................................................6
1.2.2 Chromium......................................................................7
1.2.3 Arsenic..........................................................................7
1.2.4 Zinc................................................................................8
1.2.5 Cadmium.......................................................................8
1.2.6 Copper...........................................................................9
1.2.7 Mercury.........................................................................9
1.2.8 Nickel..........................................................................10
1.3 Advantages of Recycling..........................................................10
1.4 Conclusions..............................................................................12
References...........................................................................................13
Chapter 2 Generation and Composition of Various Metal-Containing
Industrial Wastes.................................................................................19
2.1 Introduction..............................................................................19
2.2 Electronic Wastes......................................................................19
2.2.1 Printed Circuit Boards.................................................20
2.2.2 Solders.........................................................................21
2.3 Energy Storage Wastes.............................................................22
2.3.1 Batteries.......................................................................22
2.3.1.1 Zinc–Manganese Dioxide Batteries.............23
2.3.1.2 Nickel–Cadmium Batteries..........................24
2.3.1.3 Nickel–Metal Hydride Batteries..................24
2.3.1.4 Lithium-Ion Batteries...................................25
2.3.2 Button Cell Batteries...................................................26
2.4 Metal Production Wastes..........................................................26
2.4.1 Slag..............................................................................26
2.4.2 Dust.............................................................................29
2.4.3 Foundry Sand..............................................................29
2.4.4 Electric Arc Furnace Dust...........................................31
2.5 Solar Photoelectricity Wastes...................................................31
2.5.1 Solar Panels.................................................................31
2.6 Power Plant and Incineration Plant Wastes..............................32
2.6.1 Thermal Power Plant Bottom and Fly Ash..................32
2.6.2 Municipal Solid Waste................................................34
2.6.3 Coal Cleaning or Beneficiation Waste.........................35
2.7 Petrochemical Wastes...............................................................36
2.7.1 Spent Petroleum Catalysts...........................................36
2.8 Sludge.......................................................................................37
2.8.1 Municipal Sewage Sludge...........................................37
2.8.2 Industrial Sludge.........................................................38
2.9 Lighting Wastes........................................................................38
2.9.1 Light-Emitting Diodes.................................................38
2.9.2 Mercury Light Bulb Wastes.........................................39
2.10 Automobile Wastes...................................................................40
2.11 Metal Speciation.......................................................................41
References...........................................................................................44
Chapter 3 Conventional Metal Recycling Techniques.........................................63
3.1 Introduction..............................................................................63
3.2 Methods for Metal Recovery....................................................64
3.2.1 Physical/Mechanical Methods.....................................64
3.2.1.1 Screening.....................................................64
3.2.1.2 Shape Separation.........................................64
3.2.1.3 Magnetic Separation....................................64
3.2.1.4 Electric Conductivity–Based Separation.....64
3.2.1.5 Density-Based Separation............................65
3.2.2 Pyrometallurgical Method...........................................65
3.2.3 Hydrometallurgical Method........................................66
3.2.4 Microbiological and Biochemical Recycling..............69
3.2.4.1 Microbial/Bioleaching Process....................70
3.2.4.2 Mechanisms Underlying the
Bioleaching Process.....................................72
3.3 Conclusion and Future Perspective..........................................83
References...........................................................................................84
Chapter 4 Recycling of Electronic Waste............................................................97
4.1 Introduction..............................................................................97
4.2 Bioleaching of Metals from E-Waste.......................................98
4.2.1 Solder..........................................................................98
4.2.2 Printed Circuit Boards (PCBs)..................................100
4.2.2.1 Microorganisms for Metal Recovery
from PCBs.................................................100
4.2.2.2 Recovery of Gold.......................................117
4.2.3 Kinetics of Metal Recovery.......................................124
4.2.4 Process Optimization for Metal Recovery................124
4.2.5 Use of Biosurfactants in Metal Recovery..................127
4.2.6 Leaching Process Using Enzymes.............................128
4.3 Conclusion..............................................................................130
References.........................................................................................130
Chapter 5 Recycling of Energy Storage Wastes.................................................137
5.1 Introduction............................................................................137
5.2 Bioleaching of Metals from Energy Storage Wastes..............137
5.2.1 Battery.......................................................................137
5.2.1.1 Lithium-Ion Batteries.................................137
5.2.1.2 Ni–Cd and Ni–MH Batteries.....................145
5.2.1.3 Zn–Mn Batteries........................................151
5.2.2 Button Cells...............................................................154
5.3 Conclusion..............................................................................155
References.........................................................................................156
Chapter 6 Recycling of Metal Production Wastes.............................................159
6.1 Introduction............................................................................159
6.2 Bioleaching of Slags...............................................................159
6.2.1 Cu Smelter Slags.......................................................159
6.2.2 Pb/Zn Slags...............................................................166
6.3 Bioleaching of Foundry Sand.................................................168
6.4 Bioleaching of Industrial Waste Dust.....................................169
6.4.1 Smelter Dust..............................................................169
6.4.2 EAF Dust...................................................................172
6.4.3 ESP Dust...................................................................173
6.4.4 Industrial Filter Dust.................................................173
6.5 Bioleaching of Industrial Waste Sludge.................................174
6.6 Conclusion..............................................................................174
References.........................................................................................174
Chapter 7 Recycling of Solar Electricity Waste.................................................179
7.1 Introduction............................................................................179
7.2 Bioleaching of Metals from Solar Electricity Waste..............180
7.3 Conclusion..............................................................................180
References.........................................................................................181
Chapter 8 Recycling of Thermal Power Generation Wastes..............................183
8.1 Introduction............................................................................183
8.2 Bioleaching of Thermal Power Generation Waste..................183
8.2.1 Microorganisms for Metal Recovery from Fly Ash..... 183
8.2.2 Process Optimization for Metal Recovery................198
8.2.3 Kinetics of Metal Recovery.......................................200
8.3 Conclusion..............................................................................200
References.........................................................................................201
Index 205
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